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Isolation and redox reactivity of cerium complexes in four redox states

The chemistry of lanthanides is limited to one electron transfer reactions due to the difficulty of accessing multiple oxidation states. Here we report that a redox-active ligand combining three siloxides with an arene ring in a tripodal ligand can stabilize cerium complexes in four different redox...

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Detalles Bibliográficos
Autores principales: Hsueh, Fang-Che, Rajeshkumar, Thayalan, Maron, Laurent, Scopelliti, Rosario, Sienkiewicz, Andrzej, Mazzanti, Marinella
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10246686/
https://www.ncbi.nlm.nih.gov/pubmed/37293643
http://dx.doi.org/10.1039/d3sc01478a