Accessing Unusual Reactivity through Chelation-Promoted Bond Weakening

[Image: see text] Highly reducing Sm(II) reductants and protic ligands were used as a platform to ascertain the relationship between low-valent metal-protic ligand affinity and degree of ligand X–H bond weakening with the goal of forming potent proton-coupled electron transfer (PCET) reductants. Amo...

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Detalles Bibliográficos
Autores principales: Boekell, Nicholas G., Bartulovich, Caroline O., Maity, Sandeepan, Flowers, Robert A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10249415/
https://www.ncbi.nlm.nih.gov/pubmed/36912617
http://dx.doi.org/10.1021/acs.inorgchem.3c00298

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10249415/
https://www.ncbi.nlm.nih.gov/pubmed/36912617
http://dx.doi.org/10.1021/acs.inorgchem.3c00298

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