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Accessing Unusual Reactivity through Chelation-Promoted Bond Weakening
[Image: see text] Highly reducing Sm(II) reductants and protic ligands were used as a platform to ascertain the relationship between low-valent metal-protic ligand affinity and degree of ligand X–H bond weakening with the goal of forming potent proton-coupled electron transfer (PCET) reductants. Amo...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10249415/ https://www.ncbi.nlm.nih.gov/pubmed/36912617 http://dx.doi.org/10.1021/acs.inorgchem.3c00298 |