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Ligand effect on switching the rate-determining step of water oxidation in atomically precise metal nanoclusters

The ligand effects of atomically precise metal nanoclusters on electrocatalysis kinetics have been rarely revealed. Herein, we employ atomically precise Au(25) nanoclusters with different ligands (i.e., para-mercaptobenzoic acid, 6-mercaptohexanoic acid, and homocysteine) as paradigm electrocatalyst...

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Detalles Bibliográficos
Autores principales: Liu, Zhihe, Tan, Hua, Li, Bo, Hu, Zehua, Jiang, De-en, Yao, Qiaofeng, Wang, Lei, Xie, Jianping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10250400/
https://www.ncbi.nlm.nih.gov/pubmed/37291124
http://dx.doi.org/10.1038/s41467-023-38914-7