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Compressed and Expanded Lattices - Barriers to Spin-State Switching in Mn(3+) Complexes

[Image: see text] We report the structural and magnetic properties of two new Mn(3+) complex cations in the spin crossover (SCO) [Mn(R-sal(2)323)](+) series, in lattices with seven different counterions in each case. We investigate the effect on the Mn(3+) spin state of appending electron-withdrawin...

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Detalles Bibliográficos
Autores principales: Harris, Michelle M., Kühne, Irina A., Kelly, Conor T., Jakobsen, Vibe B., Jordan, Ross, O’Brien, Luke, Müller-Bunz, Helge, Felton, Solveig, Morgan, Grace G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10251414/
https://www.ncbi.nlm.nih.gov/pubmed/37304401
http://dx.doi.org/10.1021/acs.cgd.2c01284