On the Redox Properties of the Dimers of Thiazol-2-ylidenes That Are Relevant for Radical Catalysis

[Image: see text] We report the isolation and study of dimers stemming from popular thiazol-2-ylidene organocatalysts. The model featuring 2,6-di(isopropyl)phenyl (Dipp) N-substituents was found to be a stronger reducing agent (E(ox) = −0.8 V vs SCE) than bis(thiazol-2-ylidenes) previously studied i...

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Detalles Bibliográficos
Autores principales: Delfau, Ludivine, Assani, Nadhrata, Nichilo, Samantha, Pecaut, Jacques, Philouze, Christian, Broggi, Julie, Martin, David, Tomás-Mendivil, Eder
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10251502/
https://www.ncbi.nlm.nih.gov/pubmed/37303499
http://dx.doi.org/10.1021/acsorginorgau.3c00008

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10251502/
https://www.ncbi.nlm.nih.gov/pubmed/37303499
http://dx.doi.org/10.1021/acsorginorgau.3c00008

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