Cargando…
On the Redox Properties of the Dimers of Thiazol-2-ylidenes That Are Relevant for Radical Catalysis
[Image: see text] We report the isolation and study of dimers stemming from popular thiazol-2-ylidene organocatalysts. The model featuring 2,6-di(isopropyl)phenyl (Dipp) N-substituents was found to be a stronger reducing agent (E(ox) = −0.8 V vs SCE) than bis(thiazol-2-ylidenes) previously studied i...
Autores principales: | , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10251502/ https://www.ncbi.nlm.nih.gov/pubmed/37303499 http://dx.doi.org/10.1021/acsorginorgau.3c00008 |