Perfluoroalkyl Chain Length Effect on Crystal Packing and [LnO(8)] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion Magnet Behavior

Functionalized perfluoroalkyl lithium β-diketonates (LiL) react with lanthanide(III) salts (Ln = Eu, Gd, Tb, Dy) in methanol to give heterobimetallic Ln-Li complexes of general formula [(LnL(3))(LiL)(MeOH)]. The length of fluoroalkyl substituent in ligand was found to affect the crystal packing of c...

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Detalles Bibliográficos
Autores principales: Smirnova, Kristina A., Edilova, Yulia O., Kiskin, Mikhail A., Bogomyakov, Artem S., Kudyakova, Yulia S., Valova, Marina S., Romanenko, Galina V., Slepukhin, Pavel A., Saloutin, Victor I., Bazhin, Denis N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10253746/
https://www.ncbi.nlm.nih.gov/pubmed/37298728
http://dx.doi.org/10.3390/ijms24119778

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10253746/
https://www.ncbi.nlm.nih.gov/pubmed/37298728
http://dx.doi.org/10.3390/ijms24119778

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