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Intramolecular Hydrogen Bonding in N(6)-Substituted 2-Chloroadenosines: Evidence from NMR Spectroscopy

Two forms were found in the NMR spectra of N(6)-substituted 2-chloroadenosines. The proportion of the mini-form was 11–32% of the main form. It was characterized by a separate set of signals in COSY, (15)N-HMBC and other NMR spectra. We assumed that the mini-form arises due to the formation of an in...

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Detalles Bibliográficos
Autores principales: Berzina, Maria Ya., Eletskaya, Barbara Z., Kayushin, Alexei L., Dorofeeva, Elena V., Lutonina, Olga I., Fateev, Ilya V., Zhavoronkova, Olga N., Bashorin, Arthur R., Arnautova, Alexandra O., Smirnova, Olga S., Antonov, Konstantin V., Paramonov, Alexander S., Dubinnyi, Maxim A., Esipov, Roman S., Miroshnikov, Anatoly I., Konstantinova, Irina D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10253998/
https://www.ncbi.nlm.nih.gov/pubmed/37298648
http://dx.doi.org/10.3390/ijms24119697