Asymmetric Sulfoxidation by a Tyrosinase Biomimetic Dicopper Complex with a Benzimidazolyl Derivative of L-Phenylalanine

A challenge in mimicking tyrosinase activity using model compounds is to reproduce its enantioselectivity. Good enantioselection requires rigidity and a chiral center close to the active site. In this study, the synthesis of a new chiral copper complex, [Cu(2)(mXPhI)](4+/2+), based on an m-xylyl-bis...

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Detalles Bibliográficos
Autores principales: Lo Presti, Eliana, Schifano, Fabio, Bacchella, Chiara, Santagostini, Laura, Casella, Luigi, Monzani, Enrico
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10254291/
https://www.ncbi.nlm.nih.gov/pubmed/37298963
http://dx.doi.org/10.3390/molecules28114487

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10254291/
https://www.ncbi.nlm.nih.gov/pubmed/37298963
http://dx.doi.org/10.3390/molecules28114487

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