A Window into the Workings of anti-B(18)H(22) Luminescence—Blue-Fluorescent Isomeric Pair 3,3′-Cl(2)-B(18)H(20) and 3,4′-Cl(2)-B(18)H(20) (and Others) †

The action of AlCl(3) on room-temperature tetrachloromethane solutions of anti-B(18)H(22) (1) results in a mixture of fluorescent isomers, 3,3′-Cl(2)-B(18)H(20) (2) and 3,4′-Cl(2)-B(18)H(20) (3), together isolated in a 76% yield. Compounds 2 and 3 are capable of the stable emission of blue light und...

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Detalles Bibliográficos
Autores principales: Ehn, Marcel, Bavol, Dmytro, Bould, Jonathan, Strnad, Vojtěch, Litecká, Miroslava, Lang, Kamil, Kirakci, Kaplan, Clegg, William, Waddell, Paul G., Londesborough, Michael G. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10254427/
https://www.ncbi.nlm.nih.gov/pubmed/37298983
http://dx.doi.org/10.3390/molecules28114505

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10254427/
https://www.ncbi.nlm.nih.gov/pubmed/37298983
http://dx.doi.org/10.3390/molecules28114505

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