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Site-Selective Solvation-Induced Conformational Switching of Heteroleptic Heteronuclear Tb(III) and Y(III) Trisphthalocyaninates for the Control of Their Magnetic Anisotropy

In the present work, we report the synthesis of isomeric heteronuclear terbium(III) and yttrium(III) triple-decker phthalocyaninates [(BuO)(8)Pc]M[(BuO)(8)Pc]M*[(15C5)(4)Pc] (M = Tb, M* = Y or M = Y, M* = Tb, [(BuO)(8)Pc](2−)–octa-n-butoxyphthalocyaninato-ligand, [(15C5)(4)Pc](2−)–tetra-15-crown-5-p...

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Detalles Bibliográficos
Autores principales: Martynov, Alexander G., Birin, Kirill P., Kirakosyan, Gayane A., Gorbunova, Yulia G., Tsivadze, Aslan Yu.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10254442/
https://www.ncbi.nlm.nih.gov/pubmed/37298954
http://dx.doi.org/10.3390/molecules28114474