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Substituents Regulate the Cyclization of Conjugated Alkynes to Accurately Construct Cyclo-(E)-[3]dendralenes

Substituent-regulated cyclization of conjugated alkynes with acid catalysis was developed in this paper, and it provides a straightforward synthesis of cyclic-(E)-[3]dendralenes. Depending on the electronic effect of the aromatic ring pairing, a variety of phosphinyl quintuplet/hexa cyclo-[3]dendral...

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Detalles Bibliográficos
Autores principales: Xia, Yun-Tao, Li, Ya-Xin, Bi, Tong-Tong, Lian, Wei, Wang, Xia, Yan, Meng, Guo, Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10254459/
https://www.ncbi.nlm.nih.gov/pubmed/37298858
http://dx.doi.org/10.3390/molecules28114382