Substituent-Controllable Cascade Regioselective Annulation of β-Enaminones with N-Sulfonyl Triazoles for Modular Access to Imidazoles and Pyrroles

A controllable synthesis of trisubstituted imidazoles and pyrroles has been developed through rhodium(II)-catalyzed regioselective annulation of N-sulfonyl-1,2,3-trizaoles with β-enaminones. The imidazole ring was formed through a 1,1-insertion of the N-H bond to α-imino rhodium carbene, followed by...

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Detalles Bibliográficos
Autores principales: Wang, Hua, Zhou, Tongtong, Wu, Mengdi, Ye, Qingqing, He, Xinwei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10254510/
https://www.ncbi.nlm.nih.gov/pubmed/37298892
http://dx.doi.org/10.3390/molecules28114416

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10254510/
https://www.ncbi.nlm.nih.gov/pubmed/37298892
http://dx.doi.org/10.3390/molecules28114416

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