Triethylamine-Promoted Oxidative Cyclodimerization of 2H-Azirine-2-carboxylates to Pyrimidine-4,6-dicarboxylates: Experimental and DFT Study

An unprecedented oxidative cyclodimerization reaction of 2H-azirine-2-carboxylates to pyrimidine-4,6-dicarboxylates under heating with triethylamine in air is described. In this reaction, one azirine molecule undergoes formal cleavage across the C-C bond and another across the C=N bond. According to...

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Detalles Bibliográficos
Autores principales: Zakharov, Timofei N., Sakharov, Pavel A., Novikov, Mikhail S., Khlebnikov, Alexander F., Rostovskii, Nikolai V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10254727/
https://www.ncbi.nlm.nih.gov/pubmed/37298789
http://dx.doi.org/10.3390/molecules28114315

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10254727/
https://www.ncbi.nlm.nih.gov/pubmed/37298789
http://dx.doi.org/10.3390/molecules28114315

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