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Synthesis of Ultrahigh Molecular Weight Poly(methyl Methacrylate) via the Polymerization of MMA Initiated by the Combination of Palladium Carboxylates with Thiols

A novel synthesis of ultrahigh molecular weight poly(methyl methacrylate) (PMMA) using organosulfur compounds combined with a catalytical amount of transition metal carboxylates as an initiator has been developed. The combination of 1-octanethiol with palladium trifluoroacetate (Pd(CF(3)COO)(2)) was...

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Detalles Bibliográficos
Autores principales: Zhang, Panpan, Xu, Qiongqiong, Mao, Wenyu, Lv, Jiaxing, Tang, Haodong, Tang, Huadong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10255116/
https://www.ncbi.nlm.nih.gov/pubmed/37299300
http://dx.doi.org/10.3390/polym15112501