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Synthesis of Ultrahigh Molecular Weight Poly(methyl Methacrylate) via the Polymerization of MMA Initiated by the Combination of Palladium Carboxylates with Thiols
A novel synthesis of ultrahigh molecular weight poly(methyl methacrylate) (PMMA) using organosulfur compounds combined with a catalytical amount of transition metal carboxylates as an initiator has been developed. The combination of 1-octanethiol with palladium trifluoroacetate (Pd(CF(3)COO)(2)) was...
Autores principales: | Zhang, Panpan, Xu, Qiongqiong, Mao, Wenyu, Lv, Jiaxing, Tang, Haodong, Tang, Huadong |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10255116/ https://www.ncbi.nlm.nih.gov/pubmed/37299300 http://dx.doi.org/10.3390/polym15112501 |
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