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Manganese(iii) complexes stabilized with N-heterocyclic carbene ligands for alcohol oxidation catalysis
The chemistry of N-heterocyclic carbenes with Earth-abundant manganese has largely focused on low-valent systems for reductive catalysis. Here, we have decorated imidazole- and triazole-derived carbenes with phenol substituents to access higher-valent Mn(iii) complexes [Mn(O,C,O)(acac)], where acac...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10262172/ https://www.ncbi.nlm.nih.gov/pubmed/37223983 http://dx.doi.org/10.1039/d3dt01013a |