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A Cobalt Mediated Nitrene Transfer aza-Wittig Cascade Reaction To Access 1,3,4-Oxadiazole Scaffolds

[Image: see text] A cobalt(II) mediated three-component synthesis of 5-substituted-N-sulfonyl-1,3,4-oxadiazol-2(3H)-imines using sulfonyl azides, N-isocyaniminotriphenylphosphorane (NIITP), and carboxylic acids has been developed. This one-pot tandem reaction starts with a nitrene transfer to NIITP,...

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Detalles Bibliográficos
Autores principales: Verdoorn, Daniël S., Ranjan, Prabhat, de Reuver, Tim, Janssen, Elwin, Vande Velde, Christophe M. L., Saya, Jordy M., Maes, Bert U. W., Orru, Romano V. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10262268/
https://www.ncbi.nlm.nih.gov/pubmed/37224106
http://dx.doi.org/10.1021/acs.orglett.3c00959