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N-Phthalimide as a Site-Protecting and Stereodirecting Group in Rhodium-Catalyzed C–H Functionalization with Donor/Acceptor Carbenes

[Image: see text] The rhodium-catalyzed enantioselective C–H functionalization of unactivated C–H bonds by means of donor/acceptor carbene-induced C–H insertion was extended to substrates containing nitrogen functionality. The rhodium-stabilized donor/acceptor carbenes were generated by rhodium-cata...

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Detalles Bibliográficos
Autores principales: Chen, Ziyi, Cai, Qinyan, Boni, Yannick T., Liu, Wenbin, Fu, Jiantao, Davies, Huw M. L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10262272/
https://www.ncbi.nlm.nih.gov/pubmed/37253354
http://dx.doi.org/10.1021/acs.orglett.3c00844