Enantioselective Synthesis of Triarylmethanes via Intermolecular C–H Functionalization of Cyclohexadienes with Diaryldiazomethanes

[Image: see text] Rhodium-catalyzed C–H functionalization of cyclohexadiene derivatives with diaryldiazomethanes followed by oxidation with DDQ provides ready access to triarylmethanes. Two chiral dirhodium tetracarboxylates, Rh(2)(S-PTAD)(4) and Rh(2)(S-TPPTTL)(4), were found to be the optimum chir...

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Detalles Bibliográficos
Autores principales: Lee, Maizie, Davies, Huw M. L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10262276/
https://www.ncbi.nlm.nih.gov/pubmed/37249358
http://dx.doi.org/10.1021/acs.orglett.3c00845

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10262276/
https://www.ncbi.nlm.nih.gov/pubmed/37249358
http://dx.doi.org/10.1021/acs.orglett.3c00845

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