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Order–Disorder, Symmetry Breaking, and Crystallographic Phase Transition in a Series of Bis(trans-thiocyanate)iron(II) Spin Crossover Complexes Based on Tetradentate Ligands Containing 1,2,3-Triazoles
[Image: see text] We report herein a series of neutral trans-thiocyanate mononuclear spin crossover (SCO) complexes, [Fe(II)L(NCS)(2)] (1–4), based on tetradentate ligands L obtained by reaction of N-substituted 1,2,3-triazolecarbaldehyde with 1,3-propanediamine or 2,2-dimethyl-1,3-diaminopropane [L...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10265696/ https://www.ncbi.nlm.nih.gov/pubmed/37227233 http://dx.doi.org/10.1021/acs.inorgchem.3c00830 |