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Order–Disorder, Symmetry Breaking, and Crystallographic Phase Transition in a Series of Bis(trans-thiocyanate)iron(II) Spin Crossover Complexes Based on Tetradentate Ligands Containing 1,2,3-Triazoles

[Image: see text] We report herein a series of neutral trans-thiocyanate mononuclear spin crossover (SCO) complexes, [Fe(II)L(NCS)(2)] (1–4), based on tetradentate ligands L obtained by reaction of N-substituted 1,2,3-triazolecarbaldehyde with 1,3-propanediamine or 2,2-dimethyl-1,3-diaminopropane [L...

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Detalles Bibliográficos
Autores principales: Seredyuk, Maksym, Znovjyak, Kateryna, Valverde-Muñoz, Francisco Javier, Muñoz, M. Carmen, Amirkhanov, Volodymyr M., Fritsky, Igor O., Real, José Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10265696/
https://www.ncbi.nlm.nih.gov/pubmed/37227233
http://dx.doi.org/10.1021/acs.inorgchem.3c00830