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Formation of Heterobimetallic Complexes by Addition of d(10)-Metal Ions to [(Me(3)P)(x)M(2-C(6)F(4)PPh(2))(2)] (x = 1, 2; M = Ni and Pt): A Synthetic and Computational Study of Metallophilic Interactions

[Image: see text] Treatment of the bis(chelate) complexes trans-[M(κ(2)-2-C(6)F(4)PPh(2))(2)] (trans-1M; M = Ni, Pt) and cis-[Pt(κ(2)-2-C(6)F(4)PPh(2))(2)] (cis-1Pt) with equimolar amounts or excess of PMe(3) solution gave complexes of the type [(Me(3)P)(x)M(2-C(6)F(4)PPh(2))(2)] (x = 2: 2M(a), 2M(b...

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Detalles Bibliográficos
Autores principales: Gericke, Robert, Bennett, Martin A., Privér, Steven H., Bhargava, Suresh K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10265710/
https://www.ncbi.nlm.nih.gov/pubmed/37254744
http://dx.doi.org/10.1021/acs.inorgchem.3c00311