Asymmetric imino-acylation of alkenes enabled by HAT-photo/nickel cocatalysis

By merging nickel-mediated facially selective aza-Heck cyclization and radical acyl C–H activation promoted by tetrabutylammonium decatungstate (TBADT) as a hydrogen atom transfer (HAT) photocatalyst, we accomplish an asymmetric imino-acylation of oxime ester-tethered alkenes with readily available...

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Detalles Bibliográficos
Autores principales: Wang, Rui, Wang, Chuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10266448/
https://www.ncbi.nlm.nih.gov/pubmed/37325152
http://dx.doi.org/10.1039/d3sc01945d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10266448/
https://www.ncbi.nlm.nih.gov/pubmed/37325152
http://dx.doi.org/10.1039/d3sc01945d

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