Selective multifunctionalization of N-heterocyclic carbene boranes via the intermediacy of boron-centered radicals

The selective difunctionalization of N-heterocyclic carbene (NHC) boranes with alkenes has been achieved via decatungstate and thiol synergistic catalysis. The catalytic system also allows stepwise trifunctionalization, leading to complex NHC boranes with three different functional groups which are...

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Detalles Bibliográficos
Autores principales: Li, Feng-Xing, Wang, Xinmou, Lin, Jiaxin, Lou, Xiangyu, Ouyang, Jing, Hu, Guanwen, Quan, Yangjian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10266453/
https://www.ncbi.nlm.nih.gov/pubmed/37325159
http://dx.doi.org/10.1039/d3sc01132a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10266453/
https://www.ncbi.nlm.nih.gov/pubmed/37325159
http://dx.doi.org/10.1039/d3sc01132a

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