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Controlled reductive C–C coupling of isocyanides promoted by an aluminyl anion
We report the reaction of the potassium aluminyl, K[Al(NON)] ([NON](2−) = [O(SiMe(2)NDipp)(2)](2−), Dipp = 2,6-iPr(2)C(6)H(3)) with a series of isocyanide substrates (R-NC). In the case of tBu-NC, degradation of the isocyanide was observed generating an isomeric mixture of the corresponding aluminiu...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10266456/ https://www.ncbi.nlm.nih.gov/pubmed/37325153 http://dx.doi.org/10.1039/d3sc01387a |