Cobalt-catalyzed enantioselective desymmetrizing reductive cyclization of alkynyl cyclodiketones

A highly enantioselective cobalt-catalyzed desymmetrizing reductive cyclization of alkynyl cyclodiketones has been developed. Under mild reaction conditions by employing HBpin as a reducing agent and ferrocene-based PHOX as a chiral ligand, a series of polycyclic tertiary allylic alcohols bearing co...

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Detalles Bibliográficos
Autores principales: Liang, Ren-Xiao, Tang, Heng-Wei, Liu, Jia-Liang, Xu, Jian-Feng, Chen, Ling-Jia, Jia, Yi-Xia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10266457/
https://www.ncbi.nlm.nih.gov/pubmed/37325142
http://dx.doi.org/10.1039/d3sc00119a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10266457/
https://www.ncbi.nlm.nih.gov/pubmed/37325142
http://dx.doi.org/10.1039/d3sc00119a

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