Air-stable four-coordinate cobalt(ii) single-ion magnets: experimental and ab initio ligand field analyses of correlations between dihedral angles and magnetic anisotropy

For single-ion magnets (SIMs), understanding the effects of the local coordination environment and ligand field on magnetic anisotropy is key to controlling their magnetic properties. Here we present a series of tetracoordinate cobalt(ii) complexes of the general formula [(F)L(2)Co]X(2) (where (F)L...

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Detalles Bibliográficos
Autores principales: Gupta, Sandeep K., Rao, Shashank V., Demeshko, Serhiy, Dechert, Sebastian, Bill, Eckhard, Atanasov, Mihail, Neese, Frank, Meyer, Franc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10266464/
https://www.ncbi.nlm.nih.gov/pubmed/37325133
http://dx.doi.org/10.1039/d3sc00813d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10266464/
https://www.ncbi.nlm.nih.gov/pubmed/37325133
http://dx.doi.org/10.1039/d3sc00813d

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