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Air-stable four-coordinate cobalt(ii) single-ion magnets: experimental and ab initio ligand field analyses of correlations between dihedral angles and magnetic anisotropy
For single-ion magnets (SIMs), understanding the effects of the local coordination environment and ligand field on magnetic anisotropy is key to controlling their magnetic properties. Here we present a series of tetracoordinate cobalt(ii) complexes of the general formula [(F)L(2)Co]X(2) (where (F)L...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10266464/ https://www.ncbi.nlm.nih.gov/pubmed/37325133 http://dx.doi.org/10.1039/d3sc00813d |