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Unveiling catalyst-free electro-photochemical reactivity of aryl diazoesters and facile synthesis of oxazoles, imide-fused pyrroles and tetrahydro-epoxy-pyridines via carbene radical anions

Herein, we report a reagent-less (devoid of catalyst, supporting electrolyte, oxidant and reductant) electro-photochemical (EPC) reaction [electricity (50 μA) and blue LED (5 W)] of aryl diazoesters to generate radical anions which are subsequently reacted with acetonitrile or propionitrile and male...

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Detalles Bibliográficos
Autores principales: Maiti, Debajit, Saha, Argha, Guin, Srimanta, Maiti, Debabrata, Sen, Subhabrata
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10266477/
https://www.ncbi.nlm.nih.gov/pubmed/37325143
http://dx.doi.org/10.1039/d3sc00089c