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Accessing Bioactive Hydrazones by the Hydrohydrazination of Terminal Alkynes Catalyzed by Gold(I) Acyclic Aminooxy Carbene Complexes and Their Gold(I) Arylthiolato and Gold(III) Tribromo Derivatives: A Combined Experimental and Computational Study

[Image: see text] Hydrohydrazination of terminal alkynes with hydrazides yielding hydrazones 5–14 were successfully catalyzed by a series of gold(I) acyclic aminooxy carbene complexes of the type [{(4-R(2)-2,6-t-Bu(2)-C(6)H(2)O)(N(R(1))(2))}methylidene]AuCl, where R(2) = H, R(1) = Me (1b); R(2) = H,...

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Detalles Bibliográficos
Autores principales: Singh, Jyoti, Sharma, Sunita, Prakasham, A. P., Rajaraman, Gopalan, Ghosh, Prasenjit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10268297/
https://www.ncbi.nlm.nih.gov/pubmed/37323414
http://dx.doi.org/10.1021/acsomega.3c01925