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Accessing Bioactive Hydrazones by the Hydrohydrazination of Terminal Alkynes Catalyzed by Gold(I) Acyclic Aminooxy Carbene Complexes and Their Gold(I) Arylthiolato and Gold(III) Tribromo Derivatives: A Combined Experimental and Computational Study
[Image: see text] Hydrohydrazination of terminal alkynes with hydrazides yielding hydrazones 5–14 were successfully catalyzed by a series of gold(I) acyclic aminooxy carbene complexes of the type [{(4-R(2)-2,6-t-Bu(2)-C(6)H(2)O)(N(R(1))(2))}methylidene]AuCl, where R(2) = H, R(1) = Me (1b); R(2) = H,...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10268297/ https://www.ncbi.nlm.nih.gov/pubmed/37323414 http://dx.doi.org/10.1021/acsomega.3c01925 |