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Ligand Degradation Study of Unsymmetrical β-Diketiminato Copper Dioxygen Adducts: The Length Chelating Arm Effect
[Image: see text] An investigation on the reactivity of O(2) binding to unsymmetrical β-diketiminato copper(I) complexes by spectroscopic and titration analysis was performed. The length of chelating pyridyl arms (pyridylmethyl arm vs pyridylethyl arm) leads to the formation of mono- or di-nuclear c...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10268616/ https://www.ncbi.nlm.nih.gov/pubmed/37332796 http://dx.doi.org/10.1021/acsomega.3c02004 |