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Structural Features of Diacyldodecaheterocycles with Pseudo-C(2)-Symmetry: Promising Stereoinductors for Divergent Synthesis of Chiral Alcohols

[Image: see text] Pseudo-C(2)-symmetric dodecaheterocyclic structures, which possess two acyl/aroyl groups disposed on either a cis- or trans-relative configuration, were prepared from the naturally occurring (−)-(1R)-myrtenal. Addition of Grignard reagents (RMgX) to the diastereoisomeric mixture of...

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Detalles Bibliográficos
Autores principales: Flores-Bernal, Gustavo G., Vargas-Díaz, Ma. Elena, Jiménez-Vázquez, Hugo A., Hernández-Rodríguez, Marcos, Zepeda-Vallejo, L. Gerardo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10268637/
https://www.ncbi.nlm.nih.gov/pubmed/37332815
http://dx.doi.org/10.1021/acsomega.3c01161