Atom-efficient arylation of N-tosylimines mediated by cooperative ZnAr(2)/Zn(C(6)F(5))(2) combinations

By combining the Lewis acid Zn(C(6)F(5))(2) with nucleophilic diarylzinc (ZnAr(2)) reagents, we report the atom-efficient arylation of N-tosylimines under mild conditions. Mechanistic studies through the isolation of key intermediates reveal how the two zinc species act cooperatively to activate the...

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Detalles Bibliográficos
Autores principales: Borys, Andryj M., Kunzmann, Tim, Gil-Negrete, Jose M., Hevia, Eva
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10270240/
https://www.ncbi.nlm.nih.gov/pubmed/37254841
http://dx.doi.org/10.1039/d3cc01490h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10270240/
https://www.ncbi.nlm.nih.gov/pubmed/37254841
http://dx.doi.org/10.1039/d3cc01490h

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