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Atom-efficient arylation of N-tosylimines mediated by cooperative ZnAr(2)/Zn(C(6)F(5))(2) combinations
By combining the Lewis acid Zn(C(6)F(5))(2) with nucleophilic diarylzinc (ZnAr(2)) reagents, we report the atom-efficient arylation of N-tosylimines under mild conditions. Mechanistic studies through the isolation of key intermediates reveal how the two zinc species act cooperatively to activate the...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10270240/ https://www.ncbi.nlm.nih.gov/pubmed/37254841 http://dx.doi.org/10.1039/d3cc01490h |