How Is Substrate Halogenation Triggered by the Vanadium Haloperoxidase from Curvularia inaequalis?

[Image: see text] Vanadium haloperoxidases (VHPOs) are unique enzymes in biology that catalyze a challenging halogen transfer reaction and convert a strong aromatic C–H bond into C–X (X = Cl, Br, I) with the use of a vanadium cofactor and H(2)O(2). The VHPO catalytic cycle starts with the conversion...

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Detalles Bibliográficos
Autores principales: Gérard, Emilie F., Mokkawes, Thirakorn, Johannissen, Linus O., Warwicker, Jim, Spiess, Reynard R., Blanford, Christopher F., Hay, Sam, Heyes, Derren J., de Visser, Sam P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10278073/
https://www.ncbi.nlm.nih.gov/pubmed/37342830
http://dx.doi.org/10.1021/acscatal.3c00761

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10278073/
https://www.ncbi.nlm.nih.gov/pubmed/37342830
http://dx.doi.org/10.1021/acscatal.3c00761

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