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How Is Substrate Halogenation Triggered by the Vanadium Haloperoxidase from Curvularia inaequalis?
[Image: see text] Vanadium haloperoxidases (VHPOs) are unique enzymes in biology that catalyze a challenging halogen transfer reaction and convert a strong aromatic C–H bond into C–X (X = Cl, Br, I) with the use of a vanadium cofactor and H(2)O(2). The VHPO catalytic cycle starts with the conversion...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10278073/ https://www.ncbi.nlm.nih.gov/pubmed/37342830 http://dx.doi.org/10.1021/acscatal.3c00761 |