Experimental and Computational Investigation of Facial Selectivity Switching in Nickel–Diamine–Acetate-Catalyzed Michael Reactions

[Image: see text] Chiral Ni complexes have revolutionized both asymmetric acid–base and redox catalysis. However, the coordination isomerism of Ni complexes and their open-shell property still often hinder the elucidation of the origin of their observed stereoselectivity. Here, we report our experim...

Descripción completa

Detalles Bibliográficos
Autores principales: Sohtome, Yoshihiro, Komagawa, Shinsuke, Nakamura, Ayako, Hashizume, Daisuke, Lectard, Sylvain, Akakabe, Mai, Hamashima, Yoshitaka, Uchiyama, Masanobu, Sodeoka, Mikiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10278084/
https://www.ncbi.nlm.nih.gov/pubmed/36813263
http://dx.doi.org/10.1021/acs.joc.2c02732

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10278084/
https://www.ncbi.nlm.nih.gov/pubmed/36813263
http://dx.doi.org/10.1021/acs.joc.2c02732

Ejemplares similares