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Manganese catalysed dehydrogenative synthesis of polyureas from diformamide and diamines

We report here the synthesis of polyureas from the dehydrogenative coupling of diamines and diformamides. The reaction is catalysed by a manganese pincer complex and releases H(2) gas as the only by-product making the process atom-economic and sustainable. The reported method is greener in compariso...

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Detalles Bibliográficos
Autores principales: McLuskie, Angus, Brodie, Claire N., Tricarico, Michele, Gao, Chang, Peters, Gavin, Naden, Aaron B., Mackay, C. Logan, Tan, Jin-Chong, Kumar, Amit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10278093/
https://www.ncbi.nlm.nih.gov/pubmed/37342794
http://dx.doi.org/10.1039/d3cy00284e