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Isotope Effect in D(2)O Negative Ion Formation in Electron Transfer Experiments: DO–D Bond Dissociation Energy

[Image: see text] H(2)O/D(2)O negative ion time-of-flight mass spectra from electron transfer processes at different collision energies with neutral potassium yield OH(–)/OD(–), O(–), and H(–)/D(–). The branching ratios show a relevant energy dependence with an important isotope effect in D(2)O. Ele...

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Detalles Bibliográficos
Autores principales: Kumar, Sarvesh, Hoshino, Masamitsu, Kerkeni, Boutheïna, García, Gustavo, Limão-Vieira, Paulo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10278136/
https://www.ncbi.nlm.nih.gov/pubmed/37276433
http://dx.doi.org/10.1021/acs.jpclett.3c00786