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Counteranion-induced structural isomerization of phosphine-protected PdAu(8) and PtAu(8) clusters

Controlling the geometric structures of metal clusters through structural isomerization allows for tuning of their electronic state. In this study, we successfully synthesized butterfly-motif [PdAu(8)(PPh(3))(8)](2+) (PdAu8-B, B means butterfly-motif) and [PtAu(8)(PPh(3))(8)](2+) (PtAu8-B) by the st...

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Detalles Bibliográficos
Autores principales: Fujiki, Yu, Matsuyama, Tomoki, Kikkawa, Soichi, Hirayama, Jun, Takaya, Hikaru, Nakatani, Naoki, Yasuda, Nobuhiro, Nitta, Kiyofumi, Negishi, Yuichi, Yamazoe, Seiji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10281954/
https://www.ncbi.nlm.nih.gov/pubmed/37340116
http://dx.doi.org/10.1038/s42004-023-00929-y