Sodium mediated deprotonative borylation of arenes using sterically demanding B(CH(2)SiMe(3))(3): unlocking polybasic behaviour and competing lateral borane sodiation

The deprotonative metalation of organic molecules has become a convenient route to prepare functionalised aromatic substrates. Amongst the different metallating reagents available, sodium bases have recently emerged as a more sustainable and powerful alternative to their lithium analogues. Here we r...

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Detalles Bibliográficos
Autores principales: Tortajada, Andreu, Bole, Leonie J., Mu, Manting, Stanford, Martin, Peñas-Defrutos, Marconi N., García-Melchor, Max, Hevia, Eva
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10283504/
https://www.ncbi.nlm.nih.gov/pubmed/37350840
http://dx.doi.org/10.1039/d3sc01705b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10283504/
https://www.ncbi.nlm.nih.gov/pubmed/37350840
http://dx.doi.org/10.1039/d3sc01705b

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