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Sodium mediated deprotonative borylation of arenes using sterically demanding B(CH(2)SiMe(3))(3): unlocking polybasic behaviour and competing lateral borane sodiation
The deprotonative metalation of organic molecules has become a convenient route to prepare functionalised aromatic substrates. Amongst the different metallating reagents available, sodium bases have recently emerged as a more sustainable and powerful alternative to their lithium analogues. Here we r...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10283504/ https://www.ncbi.nlm.nih.gov/pubmed/37350840 http://dx.doi.org/10.1039/d3sc01705b |