Equatorial restriction of the photoinduced Jahn–Teller switch in Mn(iii)-cyclam complexes

Ultrafast transient absorption spectra were recorded for solutions of [Mn(III)(cyclam)(H(2)O)(OTf)][OTf](2) (cyclam = 1,4,8,11-tetraazacyclotetradecane and OTf = trifluoromethanesulfonate) in water to explore the possibility to restrict the equatorial expansion following photoexcitation of the d(xy)...

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Detalles Bibliográficos
Autores principales: Phelps, Ryan, Etcheverry-Berrios, Alvaro, Brechin, Euan K., Johansson, J. Olof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10284123/
https://www.ncbi.nlm.nih.gov/pubmed/37350826
http://dx.doi.org/10.1039/d3sc01506h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10284123/
https://www.ncbi.nlm.nih.gov/pubmed/37350826
http://dx.doi.org/10.1039/d3sc01506h

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