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Equatorial restriction of the photoinduced Jahn–Teller switch in Mn(iii)-cyclam complexes
Ultrafast transient absorption spectra were recorded for solutions of [Mn(III)(cyclam)(H(2)O)(OTf)][OTf](2) (cyclam = 1,4,8,11-tetraazacyclotetradecane and OTf = trifluoromethanesulfonate) in water to explore the possibility to restrict the equatorial expansion following photoexcitation of the d(xy)...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10284123/ https://www.ncbi.nlm.nih.gov/pubmed/37350826 http://dx.doi.org/10.1039/d3sc01506h |