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The contrasting reactivity of trans- vs. cis-azobenzenes (ArN[double bond, length as m-dash]NAr) with benzynes
We report here a study that has revealed two distinct modes of reactivity of azobenzene derivatives (ArN[double bond, length as m-dash]NAr) with benzynes, depending on whether the aryne reacts with a trans- or a cis-azobenzene geometric isomer. Under thermal conditions, trans-azobenzenes engage benz...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10284128/ https://www.ncbi.nlm.nih.gov/pubmed/37350825 http://dx.doi.org/10.1039/d3sc02253f |