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The contrasting reactivity of trans- vs. cis-azobenzenes (ArN[double bond, length as m-dash]NAr) with benzynes

We report here a study that has revealed two distinct modes of reactivity of azobenzene derivatives (ArN[double bond, length as m-dash]NAr) with benzynes, depending on whether the aryne reacts with a trans- or a cis-azobenzene geometric isomer. Under thermal conditions, trans-azobenzenes engage benz...

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Detalles Bibliográficos
Autores principales:	Sneddon, Dorian S., Hoye, Thomas R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10284128/ https://www.ncbi.nlm.nih.gov/pubmed/37350825 http://dx.doi.org/10.1039/d3sc02253f

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