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New Strategies for the Functionalization of Carbonyl Derivatives via α-Umpolung: From Enolates to Enolonium Ions
[Image: see text] Umpolung, a term describing the reversal of innate polarity, has become an indispensable tool to unlock new chemical space by overcoming the limitations of natural polarity. Introduced by Dieter Seebach in 1979, this principle has had a tremendous impact on synthetic organic chemis...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10286319/ https://www.ncbi.nlm.nih.gov/pubmed/37226674 http://dx.doi.org/10.1021/acs.accounts.3c00171 |