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A 13-million turnover-number anionic Ir-catalyst for a selective industrial route to chiral nicotine
Developing catalysts with both useful enantioselectivities and million turnover numbers (TONs) for asymmetric hydrogenation of ketones is attractive for industrial production of high-value bioactive chiral entities but remains a challenging. Herein, we report an ultra-efficient anionic Ir-catalyst i...
Autores principales: | , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10287737/ https://www.ncbi.nlm.nih.gov/pubmed/37349291 http://dx.doi.org/10.1038/s41467-023-39375-8 |